Activation of SO2 by [Zn(Cp*)2] and [(Cp*)ZnI-ZnI(Cp*)].
نویسندگان
چکیده
Interesting reactivity was observed in reactions of SO2 with [Zn(Cp*)2] and [(Cp*)ZnI-ZnI(Cp*)]. These reactions proceeded with insertion of SO2 into the Zn-C bonds. Spectacularly, the lability of the C-S bond in the O2SCp* ligands led to the thermal decomposition of [Zn(O2SCp*)2(tmeda)] to afford [Zn2(μ-SO3)(μ-S2O4)(tmeda)2].
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عنوان ژورنال:
- Chemical communications
دوره 52 89 شماره
صفحات -
تاریخ انتشار 2016